Homo Sapiens Surfactant Protein D

Eva Illuzzi '24 and Meera Chambers '24


Contents:


I. Introduction

Surfactant proteins (SP-A, B, C, D) are crucial to proper lung function and development. The proteins play important roles in innate immune response and reduction of alveolar surface tension in the lungs. The surfactant proteins are generally grouped as SP-A and SP-D, which aid in immune response, and SP-B and SP-C, which help lower surface tension to prevent alveolar collapse. Surfactant protein D (SP-D) is a member of the innate immune protein family, collectins, and is hydrophilic in nature. SP-D has strong antiviral and antimicrobial activity and enhances bacterial and viral clearance. SP-D works to bind and opsonize possible pathogens which leads to the facilitation of their elimination by other immune cells. SP-D can also promote or inhibit immune cell activity by binding to other immune defense cells.


II. General Structure

The SP-D protein visualized here: is shown in its Y-shaped trimer conformation and is made up of three nearly identical chains: chain A , chain B, and chain C . However, SP-D is most often found as a dodecomer made up of four homotrimeric subunits. The quaternary structure of SP-D consists of four trimers bound at their respective N-termini to form an X-shaped structure (Fig. 1).

The SP-D trimer is made up of monomers organized into four groups: the N-terminal domain, the collagenous area , the neck region , and the C-terminal domain . The C-terminal carbohydrate recognition domain (CRD) is responsible for the recognition of lung pathogens based on surface lipopolysaccharides. The interaction between the CRD and pathogen lipopolysaccharides targets the pathogen for clearance and phagocytosis.

SP-D Structure

Figure 1. Surfactant protein D structure and multimerization. Our protein model does not include the N-terminal domain or full collagen-like domain. (Sorensen, 2018)


III. Protein Domains

N-terminal Domain [Shown in Figure 1.]

Each SP-D molecule is made up of trimeric subunits that interact at the N-termini. Two conserved cysteine residues (positions 15 and 20) participate in disulfide bridges that stabilize the trimer interaction. The N terminal domain in SP-D is 25 residues in length and located at one end of the protein.

Collagen Area [Binds at End of Neck Domain]

The largest domain of SP-D is a long, highly conserved, collagenous domain in between the N-terminus and the neck of the protein. The collagen domain is important for the spatial organization of the protein and determines the separation of trimers. The highly conserved nature of the collagen domain suggests that its role in spatial organization is critical to SP-D function. Multiple post translational modifications of SP-D target the collagen-like region and N-terminal domain. These modifications include hydroxylations, glycosylations, and nitrosylations and are important in the (in)ability of the SP-D monomer to multimerize.

Neck Domain

The neck region of SP-D is an alpha helical coiled-coil, the function of which is involved in SP-D trimerization. Various SP-D protein recombinant studies have demonstrated the crucial role of the neck region in trimerization of the protein. A protein recombinant containing only the neck and CRD is still able to trimerize, while a knockoff of the neck region inhibits protein trimerization. This suggests that the neck region is critical in the formation of the SP-D trimer.

Carbohydrate Recognition Domain (CRD)

The C-terminal end of the protein, also known as the carbohydrate recognition domain (CRD), has a globular structure responsible for ligand-binding. The three C-terminals are held together by the neck region of the protein. However, the C-terminal end of the protein is not fully threefold symmetrical which demonstrates flexibility of CRDs in relation to the neck domain. There are two conserved consensus sequences located at the two ends of the carbohydrate binding groove: (Asp/Asn-Gly-Gly-Ser/Ala) and (Arg/Lys-Ala/Val-Cys-Gly-Glu-X-Arg) . These consensus sequences are critical to the recognition of specific pathogens. The binding of the SP-D CRD to lipopolysaccharides is also calcium dependent. Ca2+ ions are bound to a small depression on the CRD, which is where lipopolysaccharides bind.


IV. SP-D Real World Applications

Surfactant protein D can be used as a helpful biomarker for the characterization of various respiratory diseases. In patients with allergic asthma, increased severity of asthma can be indicated by an increased concentration of SP-D serum levels (Benfante et al. 2016). In addition, serum levels of SP-D can be used to differentiate between respiratory diseases. In patients with severe pandemic influenza A (H1N1) or severe COVID-19, plasma levels of SP-D were only elevated in influenza patients (Choreno-Parra et al. 2021). This suggests that in critically ill patients, serum levels of SP-D could be used to elucidate the cause of respiratory ailments.


V. References

Benfante A, Battaglia S, Principe S, Di Mitri C, Paterno A, Spatafora M, Scichilone N. 2016. Asthmatics with high levels of serum surfactant protein D have more severe disease. Eur Respir J. 47(6):1864-1867. doi:10.1183/13993003.02142-2015.

Choreno-Parra JA, Jimenez-Alvarez LA, Ramirez-Martinez G, Cruz-Lagunas A, Thapa M, Fernandez-Lopez LA, Carnalla-Cortes M, Choreno-Parra EM, Mena-Hernandez L, Sandoval-Vega M, et al. 2021. Expression of Surfactant Protein D Distinguishes Severe Pandemic Influenza A(H1N1) from Coronavirus Disease 2019. J Infect Dis. 224(1):21-30. doi:10.1093/infdis/jiab113.

Clark HW, Mackay R-M, Deadman ME, Hood DW, Madsen J, Moxon ER, Townsend JP, Reid KBM, Ahmed A, Shaw AJ, et al. 2016. Crystal Structure of a Complex of Surfactant Protein D (SP-D) and Haemophilus influenzae L ipopolysaccharide Reveals Shielding of Core Structures in SP-D-Resistant Strains. Infect Immun. 84(5):1585-1592. doi:10.1128/IAI.01239-15.

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Crouch EC. 2000. Surfactant protein-D and pulmonary host defense. Respir Res. 1(2):93-108. doi:10.1186/rr19.

Hakansson K, Lim NK, Hoppe HJ, Reid KB. 1999. Crystal structure of the trimeric alpha-helical coiled-coil and the three lectin domains of human lung surfactant protein D. Structure. 7(3):255-264. doi:10.1016/s0969-2126(99)80036-7.

Kishore U, Greenhough TJ, Waters P, Shrive AK, Ghai R, Kamran MF, Bernal AL, Reid KBM, Madan T, Chakraborty T. 2006. Surfactant proteins SP-A and SP-D: structure, function and receptors. Mol Immunol. 43(9):1293-1315. doi:10.1016/j.molimm.2005.08.004.

Kovacs H, O'Ddonoghue SI, Hoppe H-J, Comfort D, Reid KBM, Campbell lain D, Nilges M. 2002. Solution structure of the coiled-coil trimerization domain from lung surfactant protein D. J Biomol NMR. 24(2):89-102. doi:10.1023/a:1020980006628.

Sorensen GL. 2018. Surfactant Protein D in Respiratory and Non-Respiratory Diseases. Front Med. 5:18. doi:10.3389/fmed.2018.00018.

Wang L, Brauner JW, Mao G, Crouch E, Seaton B, Head J, Smith K, Flach CR, Mendelsohn R. 2008. Interaction of recombinant surfactant protein D with lipopolysaccharide: conformation and orientation of bound protein by IRRAS and simulations. Biochemistry. 747(31): 8103-8113. doi:10.1021/bi800626h.

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